全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药     

时磊  孙艳艳  沈小明  吕爱娟  蔡小虎  刘娇  沈加林 《岩矿测试》2020,39(6):856-865

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。  相似文献   

潮页1井钻探施工技术          下载免费PDF全文

王世炬  刘昕伟  王烁  徐明曙  纪卫军 《探矿工程》2020,47(10):33-37

潮页1井是在潮水盆地布置的第一口页岩气资源调查井，取心质量要求较高，地层有大段泥页岩层段，易水化剥落，施工难度大。本文着重介绍了潮页1井取心工艺、钻头选型、冲洗液技术及井斜控制技术等相关的施工经验。潮页1井采用大口径绳索取心技术，第四系地层以深全井取心，该技术在甘肃地区鲜有可供参考的施工案例，而该井岩心采取率接近90%。钻进过程中通过选用合理的钻进参数和护壁性能较强的冲洗液体系，解决了施工中遇到的地层“打滑”、井壁稳定性差等技术难点，保障了潮页1井的顺利完工。  相似文献   

Impacts of confining pressure and safety thickness on water and mud inrush in weathered granite     

Jinquan Liu  Weizhong Chen  Zhiping Deng  Taogen Liu 《Marine Georesources & Geotechnology》2020,38(2):144-153

Abstract

Due to the strong disintegration and water erosion of completely weathered granite, water and mud inrush disasters are apt to take place in this zone during underwater tunnel construction. The pore, compactness, seepage path length, fracture geometries and their interconnections for water and mud transfer are strongly influenced by confining pressure and waterproof-resistant slab safety thickness. In order to inspect the influence, a series of experiments based on a self-designed testing system and non-Darcy testing method were performed. The results indicated that the water and mud inrush evolution increased with the increase of confining pressure and decreased with the increase of safety thickness. In particular, the confining pressure mainly influences the initial evolution stage, and a critical safety thickness to prevent water and mud inrush is obtained. Besides, the non-Darcy testing method results shows that the water and mud inrush evolution affects the influence of non-Darcy flow. For example, while the safety thickness was smaller than the critical value, the evolution was large and unstable and its behavior transferred into nonlinear. In this case, the flow changed to non-Darcy flow.  相似文献   

茅山竹矿断层气定点观测场地勘选     

戴波  吴晓峰  张敏  孟科 《大地测量与地球动力学》2019,39(11):1202-1206

拟在茅山断裂带沿线布设若干个断层气连续观测点，建组断层气观测网。以茅山竹矿地区为例，通过断层气测量的初步结果，结合地质、人工地震、跨断层短水准等多种手段联合分析研究区断层的活动性，从而确定断层气定点观测的点位，为组建断层气观测网的选点提供借鉴和参考。  相似文献   

Experimental investigation of tsunami bore impact pressure on a perforated seawall     

《Applied Ocean Research》2019

Catastrophic failures of many tsunami barriers along the affected coasts during the 2011 Tohoku earthquake tsunami has prompted extensive investigation into improving and revising design codes for tsunami defence structures. To date, researchers and coastal engineers are investigating to understand the failure mechanisms and to find solutions so that the structures merely remain intact in the extreme event such as tsunami. Thus, the present work is motivated to experimentally study tsunami-induced bore pressures exerted on vertical seawalls; a solid vertical wall and a porous vertical seawall that consisted of a perforated front wall and a solid rear wall. Bores with various heights and velocities were generated by using the dam-break method. A porous seawall with 20% porosity of perforated front wall was used in this study. Bore pressures exerted on the solid rear wall and chamber oscillations that occurred in the experiments were also discussed. The experimental results showed that multiple peak pressures were observed during bore run-up phase in the time series of bore impacts. A predictive equation to estimate the maximum bore pressure on a perforated seawall was developed using multiple regression analysis. The proposed equation was also compared with previous empirical formulas.  相似文献   

琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素     

刘杰  杨睿  邬黛黛  金光荣  张辉 《海洋学报》2019,41(8):13-25

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律，定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上，分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后，综合各因素的历史演化过程，初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大；水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件；超过600 m水深的海域水合物稳定带厚度大部分超过 100 m，其中西北部稳定带的最大厚度超过300 m，是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果，推测其形成与天然气水合物的分解释放有关。  相似文献   

Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy     

Hongxiu Wang  Bingcheng Si  Dyan Pratt  Han Li  Xiaojun Ma 《水文研究》2020,34(2):506-516

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献   

青岛台体应变短周期气压系数变化原因探讨     

岳龙  徐清风  臧艺博  李志强  刘云  李炜  孙忠礼 《大地测量与地球动力学》2020,40(7):765-770

青岛台体应变短周期(小于128 min)气压系数2018-01出现阶变，通过对观测系统、台站周边施工情况、监测环境等逐项现场核实，排除观测系统、周边施工的影响。利用离散小波变换和回归分析发现，钻孔水位的气压系数与体应变气压系数同步阶变，结合台站钻孔施工当天体应变钻孔水位变化、体应变趋势变化、其他相邻台站水位气压系数变化等数据认为，台站钻孔施工是导致体应变气压系数变化的原因，并定性分析其变化机理。  相似文献   

渤海湾盆地歧口凹陷地层压力结构特征     

姜文亚  宋泽章  周立宏  蒲秀刚  王娜  代昆  万伟超  刘祥柏 《吉林大学学报(地球科学版)》2020,50(1):52-69

深化含油气沉积盆地的压力结构研究，厘清异常压力的空间展布，对划分含油气系统、评价有利输导体系与明确勘探甜点区带具有重要的理论和实践意义。为深化渤海湾盆地富油凹陷的油气二次勘探，本文以歧口凹陷为研究对象，对其压力结构进行重点刻画。在实测地层压力的校正下，综合单井、连井和二维地震地层压力结构分析，厘清了歧口凹陷的压力结构特征，识别出4类纵向压力结构：①单超压带结构；②双超压带结构；③多超压带结构；④静水压力结构。纵向上，歧口地区存在3类纵向压力系统样式——单超压系统、双超压系统、静水常压系统。双超压系统是歧口凹陷的主要压力系统样式，广泛发育于主凹和各大次凹；从凹陷中心向盆地边缘，双超压系统逐渐向单超压系统、静水常压系统过渡。单超压系统主要分布于盆地边缘的斜坡和潜山区，如歧北高斜坡、羊三木-扣村潜山等。静水常压系统则主要分布在离深凹区更远的沈青庄潜山和埕北斜坡区域。上部超压系统和下部超压系统的顶板分别位于东营组和沙三段内部，侧向上受盆地边缘和深大断裂控制。上部超压系统的形成主要受欠压实作用控制，以歧口主凹为中心呈环带分布；而下部超压系统的形成主要受生烃作用控制，以主凹和几大次凹为中心分布。未来，下部超压系统中保存的天然气将成为歧口地区超深层天然气勘探的重点对象。  相似文献   

页岩储层叠前密度稳定反演方法          下载免费PDF全文

李金磊  尹成  刘晓晶  陈超  王明飞 《地球物理学报》2019,62(5):1861-1871

密度参数是页岩储层评价的重要敏感参数,但通常认为准确获得密度信息难度较大.本文探索提出了一种稳定的基于弹性阻抗的叠前密度反演方法,以提高优质页岩的识别精度.首先,基于不同的参数化弹性阻抗方程开展密度敏感性分析,优选了敏感性最高的Aki-Richards近似弹性阻抗方程作为反演方程.然后,在弹性阻抗方程线性化的基础上,假设反演方程系数矩阵的逆存在,将密度(取对数)表示为多个角度弹性阻抗(取对数)的加权和,通过井旁道弹性阻抗反演结果与测井数据的回归求取加权系数,避免了常规反演方法对大型系数矩阵的求逆计算,从而提高了密度反演的稳定性,同时由于利用测井资料作为匹配目标,密度反演的精度也得到了提高.模型试算和涪陵页岩气田的实际资料应用实践均表明了该方法能够有效地提高密度反演的精度与稳定性.  相似文献